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INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY
ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON SOLUBILITY DATA
SOLUBILITY DATA SERIES
Volume 15
ALCOHOLS WitH WATER
SOLUBILITY DATA SERIES
Volume 1
Volume 2
Volume 3
Volume 4
Volume 7
Volume 8
Volume 9
Volume 10
Volume 11
Volume 12
Volume 13
Volume 14
Volume 18
H.
L.
Clever,
Helium and Neon
H.
L.
Clever,
Krypton, Xenon and Radon
M. Salomon,
Silver Azide, Cyanide, Cyanamides, Cyanate, Selenocyanate and
Thiocyanate
H.
L.
Clever,
Argon
R. Battino,
Oxygen and Ozone
C.
L.
Young,
Oxides of Nitrogen
W. Hayduk,
Ethane
R. Battino,
Nitrogen and Air
B. Scrosati and C. A. Vincent,
Alkali Metal, Alkaline Earth Metal and Ammonium
Halides. Amide Solvents
C.
L.
Young,
Sulfur Dioxide, Chlorine, Fluorine and Chlorine Oxides
S. Siekierski, T. Mioduski and M. Salomon,
Scandium, Yttrium, Lanthanum and
Lanthanide Nitrates
H. Miyamoto, M. Salomon and H.
L.
Clever,
Alkaline Earth Metal Halates
O. Popovych,
Tetraphenylborates
Volume
5/6
C.
L.
Young,
Hydrogen and Deuterium
Volume 15 A. F. M. Barton,
Alcohols with Water
Selected Volumes in Preparation
W. Gerrard and H.
L.
Clever,
Hydrogen Halides in Non-Aqueous Solvents
H. Miyamoto,
Copper and Silver Halates
W. Hayduk,
Propane, Butane and 2-Methylpropane
E. M. Woolley,
Aqueous Silver Chloride Systems
A.
L.
Horvath and F. W. Getzen,
Halobenzenes and Halophenols with Water
S. Siekierski and
J.
K. Navratil,
Actinide Nitrates
Z. Galus and C. Guminski,
Metals in Mercury
J.
W. Lorimer,
Beryllium, Strontium, Barium and Radium Sulfates
E. Tomlinson,
Beta-Lactams
C.
L.
Young and H.
L.
Clever,
Carbon Dioxide
H.
L.
Clever and C.
L.
Young,
Methane
NOTICE TO READERS
Dear Reader
If your library
~s
not already a standing-order customer or subscriber to the Solubility Data
Series, may we recommend that you place a standing order or subscription order to receive
immediately upon publication all new volumes published in this valuable series. Should you
find that these volumes no longer serve your needs, your order can be cancelled at any time
without notice.
Robert Maxwell
Publisher at Pergamon Press
~CH
m?ORMATIO!l
IltlS
CENTER
SOLUBILITY DATA SERIES
Editor-in-Chief
A.
S. KERTES
@
Volume 15
ALCOHOLS WITH WATER
_II-
Volume Editor
A. F. M. BARTON
School of Mathematical and Physical Sciences
Murdoch University, Western Australia 6150
Contributors
M. C. HAULAIT-PIRSON
University of Leuven
Belgium
G. T. HEFTER
Murdoch University
Australia
G. JANCSO
Central Institute for Physics
Budapest, Hungary
A. MACZYNSKI
Institute of Physical Chemistry
Warsaw, Poland
Z. MACZYNSKA
Institute of Physical Chemistry
Warsaw, Poland
A. SZAFRANSKI
Institute for Industrial Chemistry
Warsaw, Poland
N. TSUCHIDA
National Institute of Research
in Inorganic Materials
Ibaraki, Japan
S. C. VALVANI
UPlohn Co.
Kalamazoo, MI, USA
S. H. YALKOWSKY
Arizona University College
of Pharmacy
Tucson, AZ, USA
FU JUFU
Beijing Institute of Chemical Technology
China
PERGAMON PRESS
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U.S.A.
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Pergamon Press GmbH, Hammerweg 6,
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Copyright
©
1984 International Union of
Pure and Applied Chemistry
All Rights Reserved. No part of thIS publication may be
reproduced, stored in
a
retrieval system or transmitted in any
form or by any means: electronic, electrostatIc, magnetIc
tape, mechanical, pho to cop ymg, recording or otherwIse,
wIthout permissIon in writing from the copynght holders.
First edition 1984
Library of Congress Cataloging in Publication Data
Alcohols with water.
(Solubility data series ; v. 15)
Includes bibliographical references and indexes.
1. Alcohols - Solubility - Tables.
I. Barton, Allan F. M.
II. Haulait-Pirson, M.-C.
III. Series.
QD305.A4A4 1984
547'.031045422
84-6505
British Library Cataloguing in Publication Data
Barton, A. F. M.
Alcohols with water. - (Solubility data series; v. 15)
1. Alcohols - Solubility - Tables
I. Title
II. Series
547'.03104542'0212
QD305.A4
ISBN 0-08-025276-1
Printed m Great Britain by
A.
Wheaton
&
Co. Ltd., Exeter
CONTENTS
Foreword
Preface
Liquid-Liquid Solubility: Introductory Information
1
viii
xi
xv
1
1
Three-carbon Alcohols
1.1
1.2
2
I-Propanol
2-Propanol
2
3
Four-carbon Alcohols
2.1
2.2
2.3
2.4
2.5
2.6
2-Methyl-l-propanol
2-Methyl-2-propanol
I-Butanol
l-Butanol-d
2-Butanol
2-Butanol-d
3
29
32
92
94
118
120
120
121
122
123
126
131
140
159
162
196
203
210
210
225
226
227
228
231
234
237
240
243
247
250
253
256
257
263
291
295
3
Five-carbon Alcohols
3.1
3.2
3.3
3.4
3.5
3.6
3.7
3.8
3.9
3.10
3.11
l-Penten-3-ol
3-Penten-2-o1
4-Penten-1-o1
2,2-Dimethy1-1-propano1
2-Methy1-1-butano1
2-Methyl-2-butano1
3-Methyl-l-butanol
3-Methyl-2-butano1
l-Pentano1
2-Pentano1
3-Pentano1
4
Six-carbon Alcohols
4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.8
4.9
4.10
4.11
4.12
4.13
4.14
4.15
4.16
4.17
4.18
Cyclohexanol
4-Methyl-1-penten-3-ol
l-Hexen-3-o1
4-Hexen-3-ol
2,2-Dimethyl-l-butanol
2,3-Dimethyl-2-butano1
3,3-Dimethyl-2-butano1
2-Ethy1-1-butanol
2-Methyl-l-pentano1
2-Methyl-2-pentanol
2-Methyl-3-pentanol
3-Methyl-2-pentano1
3-Methyl-3-pentano1
4-Methy1-l-pentanol
4-Methyl-2-pentanol
1-Hexanol
2-Hexano1
3-Hexano1
v

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